Acetic Acid → HCID 178515778, 화합물

HRID 468543

반응식

HRID 468543 반응식
Cl.[NH2:2][C:3]1C(O)=CC=[CH:6][C:4]=1O.[O:11]([CH2:15][CH3:16])[C:12]([S-:14])=S.[K+].[C:18](=[O:21])([O-])[O-].[K+].[K+].C(O)(=O)C>C(O)C.O>[SH:14][C:12]1[O:11][C:15]2[CH:16]=[C:18]([OH:21])[CH:6]=[CH:4][C:3]=2[N:2]=1

참가 물질

6

반응물 4

HCID 176Acetic AcidHCID 11430Potassium CarbonateHCID 4592471,3-Benzenediol, 2-amino-, hydrochloride (1:1)HCID 2735045Potassium ethylxanthate

생성물 1

HCID 178515778HCID 178515778, 화합물

시약·촉매·용매 1

HCID 19096565Water ethanol용매

실험 절차

A mixture of aminoresorcinol hydrochloride (1.1 g), potassium ethyl xanthate (1.2 g) and potassium carbonate (1.0 g) was dissolved in ethanol/water (1:1, 20 ml) and (under an argon balloon) heated under reflux for 3 hours. The pale yellow solution was cooled to RT and then acetic acid (2 ml) was added to make the solution slightly acidic (gas evolution). A cream precipitate soon formed and the sealed flask was kept in the fridge overnight. The cream solid was collected by filtration and the damp product (0.9 g) was used immediately in the next step.

후처리

  1. temperature(under an argon balloon) heated
  2. temperatureunder reflux for 3 hours
  3. customA cream precipitate soon formed
  4. customwas kept in the fridge overnight
  5. filtrationThe cream solid was collected by filtration

출처 및 근거

ORD 기록
ord-ef36db9e8afb41c8861eff43856c8d48
출처 데이터셋
uspto-grants-2014_01
특허 번호
US08624025B2

연결된 노트

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