Dimethylformamide → N,N-dimethyl-2-(3-cyano-2-pyridyl) ethenamine

반응식

[CH3:1][C:2]1[C:7]([C:8]#[N:9])=[CH:6][CH:5]=[CH:4][N:3]=1.[CH3:10][N:11]([CH:13]=O)[CH3:12]>>[CH3:10][N:11]([CH3:13])[CH:12]=[CH:1][C:2]1[C:7]([C:8]#[N:9])=[CH:6][CH:5]=[CH:4][N:3]=1

참가 물질

반응물 2

HCID 6228Dimethylformamide

HCID 47383082-Methylpyridine-3-carbonitrile

생성물 1

HCID 54435625N,N-dimethyl-2-(3-cyano-2-pyridyl) ethenamine

실험 절차

N,N-dimethyl-2-(3-cyano-2-pyridyl)ethenamine was prepared using the procedure of 4 A from 2-methyl-3-cyanopyridine (9.0 g, 0.076 m), DMF acetal (11.0 g, 0.092 m) and DMF (50 mL) yielding N,N-dimethyl-2-(3-cyano-2-pyridyl) ethenamine b.p.=133°-135° (0.3 mm), m.p.=49°-50° after sublimation at 50° (0.3 mm).

후처리

customN,N-dimethyl-2-(3-cyano-2-pyridyl)ethenamine was prepared

출처 및 근거

ORD 기록: ord-4a2635ef6c464657ae9922b89defc428
출처 데이터셋: uspto-grants-1979_11
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04176183

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