2-Methoxybenzyl alcohol → HCID 66746302, 화합물

HRID 471653

반응식

HRID 471653 반응식
[N+]([C:4]1[CH:11]=[CH:10][CH:9]=[C:8]([N+:12]([O-:14])=[O:13])[C:5]=1[C:6]#[N:7])([O-])=O.[CH3:15][O:16][C:17]1[CH:24]=[CH:23][CH:22]=[CH:21][C:18]=1[CH2:19][OH:20]>>[N+:12]([C:8]1[CH:9]=[CH:10][CH:11]=[C:4]([O:20][CH2:19][C:18]2[CH:21]=[CH:22][CH:23]=[CH:24][C:17]=2[O:16][CH3:15])[C:5]=1[C:6]#[N:7])([O-:14])=[O:13]

참가 물질

3

반응물 2

HCID 691542-Methoxybenzyl alcoholHCID 520718Dinitrobenzonitrile

생성물 1

HCID 66746302HCID 66746302, 화합물수율 58%

실험 절차

Prepared as in Example 111c from 2,6-dinitrobenzonitrile and 2-methoxybenzyl alcohol in 58% yield. 1H NMR (400 MHz, DMSO) δ 3.82 (s, 3H), 5.34 (s, 2H), 6.99 (t, J=7.6 Hz, 1H), 7.08 (d, J=8.4 Hz, 1H), 7.37 (t, J=8.4 Hz, 1H), 7.46 (d, J=6.0 Hz, 1H), 7.81 (d, J=7.6 Hz, 1H), 7.93-7.87 (m, 2H).

출처 및 근거

ORD 기록
ord-245d3f500d9441b2bf5db76eb9258306
출처 데이터셋
uspto-grants-2014_01
특허 번호
US08633186B2

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