Prenderol → HCID 67399880, 화합물

HRID 471717

반응식

[CH2:1]([C:3]([CH2:8][CH3:9])([CH2:6][OH:7])[CH2:4][OH:5])[CH3:2].[N+:10]([C:13]1[CH:20]=[CH:19][CH:18]=[C:17]([N+]([O-])=O)[C:14]=1[C:15]#[N:16])([O-:12])=[O:11]>>[CH2:1]([C:3]([CH2:6][OH:7])([CH2:8][CH3:9])[CH2:4][O:5][C:17]1[CH:18]=[CH:19][CH:20]=[C:13]([N+:10]([O-:12])=[O:11])[C:14]=1[C:15]#[N:16])[CH3:2]

참가 물질

반응물 2

HCID 8284Prenderol

HCID 520718Dinitrobenzonitrile

생성물 1

HCID 67399880HCID 67399880, 화합물수율 86%

실험 절차

Prepared as in Example 215c from 2,2-diethylpropane-1,3-diol and 2,6-dinitrobenzonitrile in 86% yield. 1H NMR (400 MHz, DMSO-d6) δ 0.80 (t, J=7.6 Hz, 6H), 1.34 (q, J=7.6 Hz, 4H), 3.33 (d, J=5.6 Hz, 2H), 3.96 (s, 2H), 4.57 (t, J=5.2 Hz, 1H), 7.74-7.76 (m, 1H), 7.84-7.90 (m, 2H).

출처 및 근거

ORD 기록: ord-8cea73de2f8e4e7ab69a0f014b5b3edd
출처 데이터셋: uspto-grants-2014_01
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US08633186B2

연결된 노트

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