Platinous chloride → HCID 178435846, 화합물

HRID 476542

반응식

HRID 476542 반응식
[Br:1][C:2]1[C:3]2[N:7]([CH2:8][CH3:9])[C:6]([CH:10]=[C:11]3[N:37]=[C:14]([CH:15]=[C:16]4[NH:32][C:19](=[C:20]([CH2:30][CH3:31])[C:21]5[C:22]([CH2:28][CH3:29])=[C:23]([CH2:26][CH3:27])[C:24]=1[N:25]=5)[C:18]([CH2:33][CH3:34])=[C:17]4[CH2:35][CH3:36])[CH:13]=[CH:12]3)=[C:5]([CH2:38][CH3:39])[C:4]=2[CH2:40][CH3:41].[Pt:42](Cl)Cl>CN(C)C=O>[Br:1][C:2]1[C:3]2[N:7]([CH2:8][CH3:9])[C:6]([CH:10]=[C:11]3[N:37]=[C:14]([CH:15]=[C:16]4[NH:32][C:19](=[C:20]([CH2:30][CH3:31])[C:21]5[C:22]([CH2:28][CH3:29])=[C:23]([CH2:26][CH3:27])[C:24]=1[N:25]=5)[C:18]([CH2:33][CH3:34])=[C:17]4[CH2:35][CH3:36])[CH:13]=[CH:12]3)=[C:5]([CH2:38][CH3:39])[C:4]=2[CH2:40][CH3:41].[Pt:42]

참가 물질

4

반응물 2

HCID 2770Platinous chlorideHCID 178435845HCID 178435845, 화합물

생성물 1

HCID 178435846HCID 178435846, 화합물

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

In a suitable 150 ml vessel 50 ml of dimethylformamide is brought to reflux and 20 mg 5-bromo octaethylporphine free base is added and dissolved. To this solution 8 mg platinum chloride is added and permitted to react for about 20 minutes. Thereafter, the reaction mixture is permitted to cool and crystal formation promoted by the addition of 50 ml distilled water. The reaction mixture is allowed to sit for about twenty four hours to increase crystal size. The reaction mixture is filtered by vacuum filtration and the solids retained.

후처리

  1. temperatureto reflux
  2. dissolutiondissolved
  3. customto react for about 20 minutes
  4. temperatureto cool
  5. additioncrystal formation promoted by the addition of 50 ml
  6. distillationdistilled water
  7. waitto sit for about twenty four hours
  8. temperatureto increase crystal size
  9. filtrationThe reaction mixture is filtered by vacuum filtration

출처 및 근거

ORD 기록
ord-f01890c04f3b4fe4939f16b4f5a0396c
출처 데이터셋
uspto-grants-1989_12
특허 번호
US04885114

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