Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Sodium borohydride → Methyl (2-hydroxymethyl-5-methylphenoxy)acetate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Sodium borohydride | HCID 4311764 | — |
| 반응물 | Methyl (2-formyl-5-methylphenoxy)acetate | HCID 54288233 | — |
| 촉매 | Sodium Methoxide | HCID 10942334 | — |
| 용매 | Methanol | HCID 887 | — |
| 생성물 | Methyl (2-hydroxymethyl-5-methylphenoxy)acetate | HCID 54364037 | 82.9% |
반응 단계
By the method of Example 1, Step G, 11.27 g (0.054 mole) of methyl (2-formyl-5-methylphenoxy)acetate was reacted with 0.54 g (0.014 mole) of sodium borohydride and 0.10 g (0.0018 mole) of sodium methoxide in 30 mL of methanol, yielding 9.41 g of methyl (2-hydroxymethyl-5-methylphenoxy)-acetate as a yellow oil. The NMR spectrum was consistent with the proposed structure.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US05798316 |
| 출처 데이터셋 | uspto-grants-1998_08 |
| ORD ID | ord-e37de4ebdd6549958563c391f485231f |
| 출처 메모 | uspto-grants-1998_08 |