Potassium Iodide → N-[[4-bromo-3-[1-(diallylcarbamoyl)ethoxy]phenyl]]-3,4,5,6-tetrahydrophthalimide

HRID 485214

반응식

HRID 485214 반응식
[CH2:1]([N:4]([CH2:10][CH:11]=[CH2:12])[C:5](=[O:9])[CH:6](Br)[CH3:7])[CH:2]=[CH2:3].[Br:13][C:14]1[CH:19]=[CH:18][C:17]([N:20]2[C:24](=[O:25])[C:23]3[CH2:26][CH2:27][CH2:28][CH2:29][C:22]=3[C:21]2=[O:30])=[CH:16][C:15]=1[OH:31].C(=O)([O-])[O-].[K+].[K+].[I-].[K+]>CC(C)=O>[Br:13][C:14]1[CH:19]=[CH:18][C:17]([N:20]2[C:21](=[O:30])[C:22]3[CH2:29][CH2:28][CH2:27][CH2:26][C:23]=3[C:24]2=[O:25])=[CH:16][C:15]=1[O:31][CH:6]([C:5](=[O:9])[N:4]([CH2:1][CH:2]=[CH2:3])[CH2:10][CH:11]=[CH2:12])[CH3:7]

참가 물질

6

반응물 4

HCID 4875Potassium IodideHCID 11430Potassium CarbonateHCID 12769237N-(4-bromo-3-hydroxyphenyl)-3,4,5,6-tetrahydrophthalimideHCID 13036601N,N-diallyl alpha-bromopropionamide

생성물 1

HCID 13503503N-[[4-bromo-3-[1-(diallylcarbamoyl)ethoxy]phenyl]]-3,4,5,6-tetrahydrophthalimide

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

The reaction mixture was washed with water and dried and the solvent was distilled off to obtain 3.8 g. of N,N-diallyl α-bromopropionamide. The product was admixed with 3.5 g. of N-(4-bromo-3-hydroxyphenyl)-3,4,5,6-tetrahydrophthalimide, 2.2 g. of potassium carbonate, 1.8 g. of potassium iodide and 50 ml. of acetone.

후처리

  1. washThe reaction mixture was washed with water
  2. customdried
  3. distillationthe solvent was distilled off
  4. customto obtain 3.8 g

출처 및 근거

ORD 기록
ord-bf2d6795dd0b49899e460acfaecd3e6b
출처 데이터셋
uspto-grants-1985_08
특허 번호
US04536209

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