Trimethylsilylacetylene → 3-(Trimethylsilyl)ethynylbenzaldehyde

HRID 485774노트

반응식

Br[C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][CH:9]=1)[CH:5]=[O:6].[C:10]([Si:12]([CH3:15])([CH3:14])[CH3:13])#[CH:11]>>[CH3:13][Si:12]([C:10]#[C:11][C:2]1[CH:3]=[C:4]([CH:7]=[CH:8][CH:9]=1)[CH:5]=[O:6])([CH3:15])[CH3:14]

참가 물질

반응물 2

HCID 66111Trimethylsilylacetylene

HCID 765833-Bromobenzaldehyde

생성물 1

HCID 27716423-(Trimethylsilyl)ethynylbenzaldehyde

실험 절차

Compound VI was synthesized by the organopalladiumcatalyzed ethynylation of meta-bromobenzaldehyde with ethynyltrimethylsilane as follows: ##STR4##

출처 및 근거

ORD 기록: ord-22c26a963f5940f5b6cd74ebcb23944b
출처 데이터셋: uspto-grants-1985_08
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04537974

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