Trichloromethylsilane → HCID 131718361, 화합물

HRID 487766

반응식

HRID 487766 반응식
[CH2:1]([Mg]Cl)[C:2]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])[CH3:3].C(Cl)C(C1C=CC=CC=1)(C)C.[Mg].[CH3:25][Si:26](Cl)([Cl:28])[Cl:27]>C1COCC1>[CH2:1]([CH2:25][SiH:26]([Cl:28])[Cl:27])[C:2]([C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([CH3:4])[CH3:3]

참가 물질

6

반응물 4

HCID 6399TrichloromethylsilaneHCID 68191Neophyl chlorideHCID 5462224MagnesiumHCID 178418740HCID 178418740, 화합물2회

생성물 1

HCID 131718361HCID 131718361, 화합물수율 65%

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매2회

실험 절차

In accord with the procedure of Example 1, neophylmagnesium chloride was prepared from 674 g (4 mol) of neophyl chloride and 105 g (4.4 mol) of magnesium turnings in 1.5 liters of dry THF. The neophylmagnesium chloride was added to 598 g (4 mol) of methyltrichlorosilane and 2 g of cuprous cyanide in 500 ml of THF. 640 g (65% of theory) of neophylmethyldichlorosilane was obtained.

출처 및 근거

ORD 기록
ord-c8ea5e0ccad847beb6efceb6b6122ccd
출처 데이터셋
uspto-grants-1994_03
특허 번호
US05296624

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