5,7,12,14-Pentacenetetrone → Pentacene

HRID 488978

반응식

HRID 488978 반응식
[CH:1]1[C:22]2[C:21](=O)[C:20]3[C:7](=[CH:8][C:9]4[C:10](=O)[C:11]5[C:16]([C:17](=O)[C:18]=4[CH:19]=3)=[CH:15][CH:14]=[CH:13][CH:12]=5)[C:6](=O)[C:5]=2[CH:4]=[CH:3][CH:2]=1.CC(CC)[O-].CC(CC)[O-].CC(CC)[O-].[Al+3]>C1(O)CCCCC1>[CH:4]1[C:5]2[C:22](=[CH:21][C:20]3[C:7]([CH:6]=2)=[CH:8][C:9]2[C:18](=[CH:17][C:16]4[C:11]([CH:10]=2)=[CH:12][CH:13]=[CH:14][CH:15]=4)[CH:19]=3)[CH:1]=[CH:2][CH:3]=1

참가 물질

4

반응물 2

HCID 47335,7,12,14-PentacenetetroneHCID 61289Aluminum sec-butoxide

생성물 1

HCID 8671Pentacene

시약·촉매·용매 1

HCID 7966Cyclohexanol용매

반응 조건

온도
145 °C

실험 절차

To a mixture of 1.0 gram of pentacene-5,7,12,14-tetrone in 100 mL of cyclohexanol was added 7.3 grams of aluminum tri(sec-butoxide). The reaction mixture was heated to 145° C. for 66 hours. The reaction mixture was cooled to room temperature and placed in a centrifuge. A dark solid was separated and washed 3 times with cyclohexanol followed by centrifugation. The residue was washed with acetone, isolated on a filter flask, and air dried to give pentacene

후처리

  1. temperatureThe reaction mixture was cooled to room temperature
  2. customA dark solid was separated
  3. washwashed 3 times with cyclohexanol
  4. washThe residue was washed with acetone
  5. customisolated on a filter flask
  6. customair dried

출처 및 근거

ORD 기록
ord-f35f8d82034142198390f70b7e34b4a0
출처 데이터셋
uspto-grants-2005_12
특허 번호
US06974877B2

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