Aluminum sec-butoxide → 2,9-Dihexylpentacene

HRID 488982

반응식

HRID 488982 반응식
[CH2:1]([C:7]1[CH:8]=[CH:9][C:10]2[CH:11]=[C:12]3[C:25]([C:26](=O)[C:27]=2[CH:28]=1)=[CH:24][C:23]1[C:14]([C:15](=O)[C:16]2[C:21]([CH:22]=1)=[CH:20][CH:19]=[C:18]([CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH:17]=2)=[CH:13]3)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].CC(CC)[O-].CC(CC)[O-].CC(CC)[O-].[Al+3]>C1(C)C=C(C)C=C(C)C=1>[CH2:1]([C:7]1[CH:8]=[CH:9][C:10]2[C:27](=[CH:26][C:25]3[C:12]([CH:11]=2)=[CH:13][C:14]2[C:23](=[CH:22][C:21]4[C:16]([CH:15]=2)=[CH:17][C:18]([CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])=[CH:19][CH:20]=4)[CH:24]=3)[CH:28]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

참가 물질

4

반응물 2

HCID 61289Aluminum sec-butoxideHCID 22269484HCID 22269484, 화합물

생성물 1

HCID 179733722,9-Dihexylpentacene

시약·촉매·용매 1

HCID 7947Mesitylene용매

반응 조건

온도
155 °C

실험 절차

A mixture of 1.0 grams of 3,10-dihexylpentacene-5,12-dione and 2.5 grams of aluminum tri(sec-butoxide) in 50 mL of mesitylene was heated to 155° C. for 2 days and cooled. The reaction mixture was filtered and the residue washed with concentrated HCl to give 2,9-dihexylpentacene.

후처리

  1. temperaturecooled
  2. filtrationThe reaction mixture was filtered
  3. washthe residue washed with concentrated HCl

출처 및 근거

ORD 기록
ord-2c8db88bb45447ab8ec829bde259eb2e
출처 데이터셋
uspto-grants-2005_12
특허 번호
US06974877B2

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