Dimethyl Sulfate → [bis(methylsulfanyl)methylene](methyl)sulfonium Methyl Sulfate

반응식

[C:1](=[S:6])([S:4][CH3:5])[S:2][CH3:3].[S:7]([O:12]C)([O:10][CH3:11])(=[O:9])=[O:8]>>[CH3:11][O:10][S:7]([O-:12])(=[O:9])=[O:8].[CH3:3][S:2][C:1](=[S+:6][CH3:11])[S:4][CH3:5]

참가 물질

반응물 2

HCID 6497Dimethyl Sulfate

HCID 16840Dimethyl trithiocarbonate

생성물 1

HCID 86598019[bis(methylsulfanyl)methylene](methyl)sulfonium Methyl Sulfate수율 192.9%

반응 조건

온도: 90 °C

실험 절차

Dimethyl trithiocarbonate (2.76 g, 20 mmol) was treated with dimethyl sulfate (2.5 g, 20 mmol) and stirred at 90° C. for 1 h, and cooled to 25° C. The solid was broken up under ether, collected by filtration, and washed with ether to give the title compound (5.1 g, 91%).

후처리

temperaturecooled to 25° C
filtrationcollected by filtration
washwashed with ether

출처 및 근거

ORD 기록: ord-106657658c3648349601c5bf6cae158f
출처 데이터셋: uspto-grants-2009_05
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US07538105B2

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