Methanol → HCID 178448544, 화합물

HRID 516650

반응식

HRID 516650 반응식
[CH3:1][CH2:2][CH2:3][CH2:4][N:5]1[CH:9]=[N+:8]([CH3:10])[CH:7]=[CH:6]1.[Cl-].CO.[F-:14].[K+]>O>[F-:14].[CH2:4]([N+:5]1[CH:6]=[CH:7][N:8]([CH3:10])[CH:9]=1)[CH2:3][CH2:2][CH3:1]

참가 물질

5

반응물 3

HCID 887MethanolHCID 522689Potassium FluorideHCID 27341611-Butyl-3-methylimidazolium chloride2회

생성물 1

HCID 178448544HCID 178448544, 화합물수율 94%

시약·촉매·용매 1

HCID 962Water용매

반응 조건

온도
22 °C

실험 절차

10.3 grams of [BMIMCl] prepared as described above were added to a mixture of 28 mL methanol and 0.06 mL water. After complete dissolution of the [BMIMCl], 5.0 grams of dry potassium fluoride (KF) were added, and the reaction mixture was stirred at 22° C. for 20 minutes. The mixture was filtered. 4.4 grams of KF was added to the filtrate, and the mixing continued for additional 20 minutes. After filtration, the methanol was evaporated under vacuum at room temperature, and the mixture was then filtered and centrifuged. The resulting yellowish liquid was determined by elementary analysis to be the titled compound [BMIMF] in 94% yield.

후처리

  1. additionwere added
  2. filtrationThe mixture was filtered
  3. addition4.4 grams of KF was added to the filtrate
  4. waitthe mixing continued for additional 20 minutes
  5. filtrationAfter filtration
  6. customthe methanol was evaporated under vacuum at room temperature
  7. filtrationthe mixture was then filtered

출처 및 근거

ORD 기록
ord-1ab9d796dbeb4188a89ff06eca4121c7
출처 데이터셋
uspto-grants-2015_08
특허 번호
US09114360B2

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