Benzonitrile → 7-Bromo-2-phenyl-[1,2,4]triazolo[1,5-A]pyridine

HRID 517636

반응식

HRID 517636 반응식
[NH2:1][C:2]1[CH:7]=[C:6]([Br:8])[CH:5]=[CH:4][N:3]=1.O.N1C2C(=CC=C3C=2N=CC=C3)C=CC=1.[C:24](#[N:31])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>[Cu]Br.[I-].[Zn+2].[I-].ClC1C=CC=CC=1Cl>[Br:8][C:6]1[CH:5]=[CH:4][N:3]2[N:31]=[C:24]([C:25]3[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=3)[N:1]=[C:2]2[CH:7]=1

참가 물질

7

반응 조건

온도
130 °C

실험 절차

A mixture of 2-amino-4-bromopyridine (0.50 g, 2.89 mmol), copper (I) bromide (20.7 mg, 0.14 mmol), 1,10-phenanthroline monohydrate (28.9 mg, 0.14 mmol), zinc iodide (92.3 mg, 0.29 mmol), benzonitrile (298 mg, 0.29 mL, 2.89 mmol) and 1,2-dichlorobenzene (25 mL) was heated in a 100-mL 3-necked flask to 130° C. During 22 h a gentle flow of air was bubbled through the reaction mixture (69% conversion, HPLC method cf. example 1.3). The dark brown suspension was then cooled to 0-5° C. and filtered. The filter cake was washed with EtOAc (30 mL) and the combined filtrates were concentrated on vacuum such that most EtOAc was evaporated off. The resulting solution of the crude product in 1,2-dichlorobenzene was then loaded on a silica gel column to yield after chromatography (hexane/EtOAC from 9:1 to 7:3) 7-bromo-2-phenyl-[1,2,4]triazolo[1,5-a]pyridine (345 mg, 41%) as an off-white solid with 97.6% purity (HPLC area-%, HPLC method cf. comparative example 1) containing as an non-separable impurity 1.4% of 7-iodo-2-phenyl-[1,2,4]triazolo[1,5-a]pyridine.

후처리

  1. customDuring 22 h a gentle flow of air was bubbled through the reaction mixture (69% conversion, HPLC method cf. example 1.3)
  2. temperatureThe dark brown suspension was then cooled to 0-5° C.
  3. filtrationfiltered
  4. washThe filter cake was washed with EtOAc (30 mL)
  5. concentrationthe combined filtrates were concentrated on vacuum such that most EtOAc
  6. customwas evaporated off

출처 및 근거

ORD 기록
ord-eb8bdab1de8b4d8c9a87b27b2def9294
출처 데이터셋
uspto-grants-2015_08
특허 번호
US09115130B2

연결된 노트

불러오는 중…