N-bromobutanimide → 3-Bromo-1,6-diphenylpyrene

HRID 530184노트

반응식

HRID 530184 반응식
[C:1]1([C:7]2[C:20]3[C:21]4=[C:22]5[C:17](=[CH:18][CH:19]=3)[CH:16]=[CH:15][C:14]([C:23]3[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=3)=[C:13]5[CH:12]=[CH:11][C:10]4=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:29]N1C(=O)CCC1=O>CN(C=O)C>[Br:29][C:16]1[CH:15]=[C:14]([C:23]2[CH:24]=[CH:25][CH:26]=[CH:27][CH:28]=2)[C:13]2[C:22]3=[C:21]4[C:10]([CH:9]=[CH:8][C:7]([C:1]5[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=5)=[C:20]4[CH:19]=[CH:18][C:17]=13)=[CH:11][CH:12]=2

참가 물질

4

반응물 2

HCID 67184N-bromobutanimideHCID 591334031,6-Diphenylpyrene

생성물 1

HCID 866682753-Bromo-1,6-diphenylpyrene

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

Under a flow of argon, 11.8 g of 1,6-diphenylpyrene, 5.93 g of N-bromosuccinimide and DMF were placed into a flask. The resulting mixture was allowed to react at 60° C. for 2 days. After cooling, the reaction solution was filtered, and solids obtained were washed with clean water, methanol and clean water, and solids obtained were dried under a reduced pressure, whereby white solids of 3-bromo-1,6-diphenylpyrene (8.60 g) were obtained.

후처리

  1. customto react at 60° C. for 2 days
  2. temperatureAfter cooling
  3. filtrationthe reaction solution was filtered
  4. customsolids obtained
  5. washwere washed with clean water, methanol and clean water, and solids
  6. customobtained
  7. dry with materialwere dried under a reduced pressure, whereby white solids of 3-bromo-1,6-diphenylpyrene (8.60 g)
  8. customwere obtained

출처 및 근거

ORD 기록
ord-1b16e8a6b231404c81fc18bcb948d2f7
출처 데이터셋
uspto-grants-2016_05
특허 번호
US09353027B2

반응 노트

불러오는 중…