Ethanol → Benzenesulfonamide, 4-methyl-N-phenyl-

HRID 53096

반응식

HRID 53096 반응식
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:8][C:9]1[CH:14]=[CH:13][C:12]([S:15](Cl)(=[O:17])=[O:16])=[CH:11][CH:10]=1.C(O)C>[OH-].[Na+]>[C:9]1([CH3:8])[CH:14]=[CH:13][C:12]([S:15]([NH:1][C:2]2[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=2)(=[O:17])=[O:16])=[CH:11][CH:10]=1

참가 물질

5

반응물 3

HCID 702EthanolHCID 6115AnilineHCID 73974-Toluenesulfonyl chloride

생성물 1

HCID 2456Benzenesulfonamide, 4-methyl-N-phenyl-

시약·촉매·용매 1

HCID 14798Sodium Hydroxide용매

실험 절차

Aniline (5 g, 54 mmol) was reacted with p-toluenesulfochloride (15 g, 78 mmol) in 10% sodium hydroxide solution under standard conditions (Vogel, Id, at p. 1275). The product (8.9 g, 36 mmol) was twice recrystallized from ethanol; the melting point was 102°-103° C., yield, 67%.

후처리

  1. customthe melting point was 102°-103° C., yield

출처 및 근거

ORD 기록
ord-da65fb542baf407499701a08080f5181
출처 데이터셋
uspto-grants-1997_04
특허 번호
US05618726

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