Hydrogen Cyanide → Methyl Methacrylate

HRID 53361

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HRID 53361 반응식
[C-:1]#[N:2].[K+].C#N.[C:6]([O:11][CH3:12])(=[O:10])[C:7]([CH3:9])=[CH2:8]>CN1CCCC1=O>[C:1]([C:7]([CH3:9])([CH3:8])[C:6]([O:11][CH3:12])=[O:10])#[N:2].[C:6]([O:11][CH3:12])(=[O:10])[C:7]([CH3:9])=[CH2:8]

참가 물질

6

반응물 3

HCID 768Hydrogen CyanideHCID 6658Methyl MethacrylateHCID 9032Potassium Cyanide

생성물 2

HCID 6658Methyl MethacrylateHCID 109645102-Cyano-2-methyl-propanoic acid methyl ester

시약·촉매·용매 1

HCID 13387N-methyl-2-pyrrolidone용매

반응 조건

온도
120 °C

실험 절차

A 500 milliliter (hereinafter abbreviated to "mL") flask equipped with a stirrer, a thermometer and two dropping funnels was charged with 203 g of N-methylpyrrolidone and 1.35 g of potassium cyanide, and to the content in the flask were added dropwise 40 g of prussic acid and 163 g of methyl methacrylate over a period of 4 hours, while the content was maintained at a temperature of 120° C. After the completion of the dropwise addition, the content was maintained at 120° C. for 2 hours to complete the reaction. As a result, methyl cyanoisobutyrate was formed at a conversion of methyl methacrylate (MMA) of 88.3% and at a selectivity of 98.1% based on the reacted MMA.

후처리

  1. customA 500 milliliter (hereinafter abbreviated to "mL") flask equipped with a stirrer
  2. additionAfter the completion of the dropwise addition
  3. temperaturethe content was maintained at 120° C. for 2 hours
  4. customthe reaction

출처 및 근거

ORD 기록
ord-f1580a895d3643059add5c06253fd208
출처 데이터셋
uspto-grants-1997_04
특허 번호
US05618953

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