Methanesulfonic Acid → Methyl Ricinoleate

HRID 534283노트

반응식

HRID 534283 반응식
[C:1](PCC1C(CPC(C)(C)C)=CC=CC=1)(C)(C)C.CS(O)(=O)=O.[C:24]([O-:44])(=[O:43])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31]/[CH:32]=[CH:33]\[CH2:34][C@@H:35]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])[OH:36]>CC([O-])=O.CC([O-])=O.[Pd+2]>[CH3:1][O:43][C:24](=[O:44])[CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31]/[CH:32]=[CH:33]\[CH2:34][C@@H:35]([CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH3:42])[OH:36]

참가 물질

5

반응물 3

HCID 6395Methanesulfonic AcidHCID 16690250alpha,alpha'-Di-tert-butylphosphino-o-xyleneHCID 25630959Ricinoleate

생성물 1

HCID 5354133Methyl Ricinoleate

시약·촉매·용매 1

HCID 167845palladium(II) acetate촉매

실험 절차

Pd(OAc)2 (0.45 mg, 0.002 mmol) and α,α′-di-tert-butylphosphino-o-xylene (4 mg, 0.01 mmol) were dissolved in 4 mL of either one of the solvents of Table 5. Subsequently, methanesulfonic acid (1.3 μL, 0.02 mmol) and ricinoleate (1 mmol, 338 μL) were added. The reaction was allowed to proceed at the temperature and time as indicated in Table 5. The reaction mixtures were cooled down to room temperature and analyzed by means of GC. The results are summarized in Table 5.

후처리

  1. customThe reaction mixtures

출처 및 근거

ORD 기록
ord-12e0930a249d43f49be52732320dcaeb
출처 데이터셋
uspto-grants-2014_10
특허 번호
US08853434B2

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