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Hydrochloric Acid → Pyridinium Trifluoromethanesulfonate

HRID 537710
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HRID 537710 반응식
C1([Si](OC)(OC)OC)C=CC=CC=1.C(O[Si](OCC)(OCC)OCC)C.C[Si](OCC)(OCC)OCC.[F:38][C:39]([F:45])([F:44])[S:40]([O-:43])(=[O:42])=[O:41].CO[Si](CC[C:55]1[CH:60]=[CH:59][CH:58]=[CH:57][N+:56]=1C)(OC)OC.Cl.C(OCC(O)C)C>O.CC(C)=O.CO.C(O)C>[F:38][C:39]([F:45])([F:44])[S:40]([O-:43])(=[O:42])=[O:41].[NH+:56]1[CH:57]=[CH:58][CH:59]=[CH:60][CH:55]=1
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참가 물질

11

반응물 6

HCID 313Hydrochloric Acid2회HCID 6517TetraethoxysilaneHCID 152871-Ethoxy-2-propanolHCID 16241TriethoxymethylsilaneHCID 18137TrimethoxyphenylsilaneHCID 86654379HCID 86654379, 화합물

생성물 1

HCID 2734866
Pyridinium Trifluoromethanesulfonate

시약·촉매·용매 4

HCID 180Acetone용매2회HCID 702Ethanol용매HCID 887Methanol용매2회HCID 962Water용매

실험 절차

4.92 g of phenyltrimethoxysilane, 72.39 g of tetraethoxysilane, 22.04 g of methyltriethoxysilane, 0.56 g of the 30% methanol solution of trimethoxysilylethylmethylpyridinium trifluoromethanesulfonate, and 150 g of acetone were charged into a 500 mL flask to be dissolved and the resultant mixed solution was warmed while stirring the mixed solution with a magnetic stirrer to reflux. Next, 33.13 g of 0.01 M hydrochloric acid was added to the mixed solution. The mixed solution was subjected to the reaction for 240 minutes and then the resultant reaction solution was cooled down to room temperature. Then, 200 g of propylene glycol monoethyl ether was added to the reaction solution, and ethanol and methanol as reaction by-products, acetone, water, and hydrochloric acid were distilled off under reduced pressure to obtain a hydrolysis-condensation product. The polymer thus obtained corresponded to Formula (VII-22):

후처리

  1. dissolutionto be dissolved
  2. additionthe resultant mixed solution
  3. temperaturewas warmed
  4. temperatureto reflux
  5. customThe mixed solution was subjected to the reaction for 240 minutes
  6. customthe resultant reaction solution
  7. distillationwere distilled off under reduced pressure
  8. customto obtain a hydrolysis-condensation product
  9. customThe polymer thus obtained

출처 및 근거

ORD 기록
ord-76385a962aed4d7eaccb2f4f3d9bebaa
출처 데이터셋
uspto-grants-2014_10
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US08864894B2

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