1-Butanaminium, N,N,N-tributyl-, azide → Ethanethioic acid cis-(+/-)-S-[5-(Azidomethyl)tetrahydro-3-furanyl]ester

HRID 54778

반응식

HRID 54778 반응식
FC(F)(F)S(O[CH2:7][C@H:8]1[O:12][CH2:11][C@@H:10]([S:13][C:14](=[O:16])[CH3:15])[CH2:9]1)(=O)=O.[N-:19]=[N+:20]=[N-:21].C([N+](CCCC)(CCCC)CCCC)CCC>C(Cl)Cl>[N:19]([CH2:7][C@H:8]1[O:12][CH2:11][C@@H:10]([S:13][C:14](=[O:16])[CH3:15])[CH2:9]1)=[N+:20]=[N-:21]

참가 물질

4

반응물 2

HCID 57432321-Butanaminium, N,N,N-tributyl-, azideHCID 86750330HCID 86750330, 화합물

생성물 1

HCID 86750331Ethanethioic acid cis-(+/-)-S-[5-(Azidomethyl)tetrahydro-3-furanyl]ester수율 87.8%

시약·촉매·용매 1

HCID 6344Dichloromethane용매2회

실험 절차

The title compound is prepared by the procedure of Example 43 using 0.560 g of product from Example 60 in 2 ml of methylene chloride, 0.569 g of tetrabutylammonium azide in 2 ml of methylene chloride to give 0.321 g of the desired product.

출처 및 근거

ORD 기록
ord-8808e9b3904943e3bfecb2393f2ea08f
출처 데이터셋
uspto-grants-1997_04
특허 번호
US05623081

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