a Farnesol → 3,7,11-Trimethyl-1-dodecanol

HRID 5628

반응식

HRID 5628 반응식
[OH:1][CH2:2][CH:3]=[C:4]([CH2:6][CH2:7][CH:8]=[C:9]([CH2:11][CH2:12][CH:13]=[C:14]([CH3:16])[CH3:15])[CH3:10])[CH3:5]>C(O)C.[Pt]=O>[CH3:5][CH:4]([CH2:6][CH2:7][CH2:8][CH:9]([CH3:10])[CH2:11][CH2:12][CH2:13][CH:14]([CH3:16])[CH3:15])[CH2:3][CH2:2][OH:1]

참가 물질

4

반응물 1

HCID 3327a Farnesol

생성물 1

HCID 1388243,7,11-Trimethyl-1-dodecanol수율 94.9%

시약·촉매·용매 2

HCID 82844Platinum oxide (PtO)촉매HCID 702Ethanol용매

실험 절차

Farnesol (200 g) was dissolved in ethanol (1000 ml), added with platinum oxide (1 g) and stirred for 24 hours at room temperature under hydrogen atmosphere. After the completion of the reaction, insoluble material was removed by filtration through a Celite layer and the filtrate was concentrated under reduced pressure to obtain 3,7,11-trimethyldodecanol (195 g).

후처리

  1. customAfter the completion of the reaction, insoluble material
  2. customwas removed by filtration through a Celite layer
  3. concentrationthe filtrate was concentrated under reduced pressure

출처 및 근거

ORD 기록
ord-d6aa1484224448e995eff7bbe4db6fd5
출처 데이터셋
uspto-grants-1993_09
특허 번호
US05245070

연결된 노트

불러오는 중…