Benzoyl Peroxide → 1,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

HRID 566536노트

반응식

HRID 566536 반응식
[C:1]1([C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:8][CH3:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:34]N1C(=O)CCC1=O>C(Cl)(Cl)(Cl)Cl>[Br:34][CH2:9][CH:8]=[C:7]([C:10]1[CH:11]=[CH:12][CH:13]=[CH:14][CH:15]=1)[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

참가 물질

5

반응물 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 2382071,1-Diphenyl-1-propene

생성물 1

HCID 123465451,1'-(3-Bromoprop-1-ene-1,1-diyl)dibenzene

시약·촉매·용매 1

HCID 5943Carbon Tetrachloride용매

실험 절차

A mixture of 1,1-diphenyl-1-propene (17.0 g, 0.10 mol), carbontetrachloride (100 ml), benzoylperoxide (0.2 g) and N-bromosuccinimide (17.8 g, 0.10 mol) was heated at reflux temperature for 18 h. The reaction mixture was allowed to cool to room temperature, filtered and the solvent was evaporated in vacuo to give 3-bromo-1, 1-diphenyl-1-propene in a quantitative yield.

후처리

  1. temperaturewas heated
  2. temperatureat reflux temperature for 18 h
  3. filtrationfiltered
  4. customthe solvent was evaporated in vacuo

출처 및 근거

ORD 기록
ord-af3f193276504907b8aa0a030f1ba784
출처 데이터셋
uspto-grants-2001_01
특허 번호
US06174898B1

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