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Dicyclopentadiene → HCID 18784409, 화합물

HRID 567646
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HRID 567646 반응식
[CH2:1]1[CH:5]2[CH:6]3[CH:10]=[CH:9][CH:8]([CH:4]2[CH:3]=[CH:2]1)[CH2:7]3.[CH3:11][C:12]1([C:19]([O:21][CH3:22])=[O:20])CC2C[CH:13]1C=C2.C1CC=CC=1.COC1C=CC(O)=CC=1>C(OC)(=O)C(C)=C>[CH3:11][C:12]1([C:19]([O:21][CH3:22])=[O:20])[CH2:13][CH:1]2[CH2:2][CH:3]1[CH:4]1[CH:5]2[CH:6]2[CH2:7][CH:8]1[CH:9]=[CH:10]2
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6

반응물 4

HCID 6492DicyclopentadieneHCID 7612CyclopentadieneHCID 90154-MethoxyphenolHCID 530353Methyl 2-methylbicyclo[2.2.1]hept-5-ene-2-carboxylate

생성물 1

HCID 18784409HCID 18784409, 화합물

시약·촉매·용매 1

HCID 6658Methyl Methacrylate용매2회

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온도
180 °C

실험 절차

A 50 liter reaction vessel equipped with a stirrer maintained at a temperature of 180° C. and pressure of 3.5 kg/cm2.G was continuously charged with a mixture of methyl methacrylate, dicyclopentadiene, and 5-methyl-5-methoxycarbonylbicyclo[2.2.1]hept-2-ene, at a ratio of 1:2.4 (cyclopentadiene base):2.4, at a feed rate of 4 kg/hour, so that the average residence time of the reaction raw materials in the reaction vessel was maintained 8 hours. As a polymerization inhibitor, a solution of p-methoxyphenol in methyl methacrylate was added in an amount of 300 ppm (weight base) of the total amount of the reaction raw materials.

후처리

  1. customA 50 liter reaction vessel
  2. customequipped with a stirrer
  3. custom2.4, at a feed rate of 4 kg/hour, so that the average residence time of the reaction raw materials in the reaction vessel
  4. temperaturewas maintained 8 hours

출처 및 근거

ORD 기록
ord-5bdcf9eef869454c99f31996a2133956
출처 데이터셋
uspto-grants-2001_01
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06180316B2

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