1-Octene → Octane

HRID 567658

반응식

HRID 567658 반응식
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>C1CCCCC1.CCCCCCC.[CH-]1[C-]=[C-][C-]=[C-]1.[CH-]1[C-]=[C-][C-]=[C-]1.Cl[Ti]Cl>[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[CH3:1][CH:2]=[CH:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

참가 물질

6

반응물 1

HCID 81251-Octene

생성물 2

HCID 356OctaneHCID 8126Oct-2-ene

시약·촉매·용매 3

HCID 416358Bis(cyclopentadienyl)titanium(IV) chloride촉매HCID 8078Cyclohexane용매2회HCID 8900Heptane용매

실험 절차

0.12 mmoles of bis-(η5-cyclopentadienyl)titanium dichloride (Cp2TiCl2; Aldrich commercial product), 20 ml of anhydrous cyclohexane, 0.03 ml of a solution of n-dibutylglima 0.45 M in anhydrous cyclohexane and 0.54 ml of 1 molar Mg(butyl)2 in n-heptane (atomic ratio Mg/Ti=4.5), are charged into a tailed test-tube equipped with a magnetic stirrer, in an atmosphere of argon. The mixture is left under stirring for 20 hours at room temperature. 18.8 ml of 1-octene (distilled and maintained on molecular sieves) are added. At this point the solution is siphoned in an autoclave previously maintained under argon and the same procedure is carried out as described in example 1 above. At the end it is cooled to room temperature. About 14 ml of octane and 4 ml of 2-octene are obtained by distillation (GC, mass GC and NMR analyses). The results and process conditions are summarized in table 1 below.

후처리

  1. customequipped with a magnetic stirrer, in an atmosphere of argon
  2. waitThe mixture is left
  3. temperaturepreviously maintained under argon
  4. temperatureAt the end it is cooled to room temperature

출처 및 근거

ORD 기록
ord-eeb13e21c0b84dd1bbb2834d05d724ac
출처 데이터셋
uspto-grants-2001_01
특허 번호
US06180553B2

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