Hydrazine → 3,6-Dichloro-2-methoxybenzoylhydrazine

HRID 568745

반응식

HRID 568745 반응식
[NH2:1][NH2:2].[Cl:3][C:4]1[C:5]([O:14][CH3:15])=[C:6]([C:10]([Cl:13])=[CH:11][CH:12]=1)[C:7](Cl)=[O:8]>C(Cl)(Cl)Cl>[Cl:3][C:4]1[C:5]([O:14][CH3:15])=[C:6]([C:10]([Cl:13])=[CH:11][CH:12]=1)[C:7]([NH:1][NH2:2])=[O:8]

참가 물질

4

반응물 2

HCID 9321HydrazineHCID 82609Benzoyl chloride, 3,6-dichloro-2-methoxy-

생성물 1

HCID 201489863,6-Dichloro-2-methoxybenzoylhydrazine

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

To a solution of 0.22 mol. hydrazine in 100 ml. chloroform at -10° C. was added 0.1 mol. of 3,6-dichloro-2-methoxybenzoyl chloride. The mixture was stirred at ambient temperature for 2 hours, filtered, and the filtrate evaporated in vacuo. The residue was crystallized from methanol and water, then recrystallized from chloroform and hexane to obtain the titled product, m.p. 144°-145° C.

후처리

  1. filtrationfiltered
  2. customthe filtrate evaporated in vacuo
  3. customThe residue was crystallized from methanol and water
  4. customrecrystallized from chloroform and hexane

출처 및 근거

ORD 기록
ord-4250b9ac8cb8488f80d965ffe4cfe6f6
출처 데이터셋
uspto-grants-1988_03
특허 번호
US04729781

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