Trifluoroacetic acid → Butyltin trichloride

반응식

[CH2:1]([Sn:5]([Cl:8])([Cl:7])[Cl:6])[CH2:2][CH2:3][CH3:4].[Na].[F:10][C:11]([F:16])([F:15])[C:12]([OH:14])=[O:13]>>[F:10][C:11]([F:16])([F:15])[C:12]([O-:14])=[O:13].[CH2:1]([Sn+:5]([Cl:7])[Cl:6])[CH2:2][CH2:3][CH3:4].[CH2:1]([Sn:5]([Cl:8])([Cl:7])[Cl:6])[CH2:2][CH2:3][CH3:4]

참가 물질

반응물 3

HCID 6422Trifluoroacetic acid

HCID 14236Butyltin trichloride

HCID 5360545Sodium

생성물 2

HCID 14236Butyltin trichloride

HCID 20148371Monobutyldichlorotin trifluoroacetate

실험 절차

A reaction mixture of monobutyltin trichloride (200 g., 0.7 moles) and the sodium salt of trifluoroacetic acid (10 g., 0.07 moles) were heated at 70° C. for 3 hours and allowed to stand overnight at room temperature. The sodium chloride by-product and unreacted sodium salt were filtered. A liquid coating composition of about 12 wt.% monobutyldichlorotin trifluoroacetate and 88 wt% monobutyltin trichloride was produced in situ.