Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
3-Phenoxy-alpha-ethynylbenzylalcohol → alpha-ethynyl-3-phenoxy-benzyl(1R,cis)2,2-dimethyl-3-[(Z)3-oxo-3-(2-fluoroethoxy)-1-propenyl]-cyclopropane-carboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 3-Phenoxy-alpha-ethynylbenzylalcohol | HCID 12919092 | — |
| 반응물 | HCID 86740321 | HCID 86740321 | — |
| 용매 | Chloroform | HCID 6212 | — |
| 생성물 | alpha-ethynyl-3-phenoxy-benzyl(1R,cis)2,2-dimethyl-3-[(Z)3-oxo-3-(2-fluoroethoxy)-1-propenyl]-cyclopropane-carboxylate | HCID 86740322 | — |
반응 단계
Using the procedure of Step F of Example 9, (1R,cis)2,2-dimethyl-3-[(Z)3-oxo-3-(2-fluoroethoxy)-1-propenyl]-cyclopropane-carboxylic acid and α-ethynyl-3-phenoxy-benzyl alcohol were reacted to obtain α-ethynyl-3-phenoxy-benzyl(1R,cis)2,2-dimethyl-3-[(Z)3-oxo-3-(2-fluoroethoxy)-1-propenyl]-cyclopropane-carboxylate with a specific rotation of [α]D20 =+47°±1.5° (c=1% in CHCl3).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US04732903 |
| 출처 데이터셋 | uspto-grants-1988_03 |
| ORD ID | ord-cbca38010e6c43b1ab5197060e8151d1 |
| 출처 메모 | uspto-grants-1988_03 |