9-Phenylanthracene → 9-Bromo-10-phenyl-anthracene

HRID 571588

반응식

HRID 571588 반응식
[C:1]1([C:7]2[C:8]3[C:13]([CH:14]=[C:15]4[C:20]=2[CH:19]=[CH:18][CH:17]=[CH:16]4)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Br:21]C1CC(=O)NC1=O>CN(C)C=O>[Br:21][C:14]1[C:15]2[C:20]([C:7]([C:1]3[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=3)=[C:8]3[C:13]=1[CH:12]=[CH:11][CH:10]=[CH:9]3)=[CH:19][CH:18]=[CH:17][CH:16]=2

참가 물질

4

반응물 2

HCID 117669-PhenylanthraceneHCID 38309Bromosuccinimide

생성물 1

HCID 41558369-Bromo-10-phenyl-anthracene수율 89.3%

시약·촉매·용매 1

HCID 6228Dimethylformamide용매

실험 절차

An amount of 13.65 (53.7 mmol) of 9-phenylanthracene was dissolved in 100 ml of N,N dimethylformamide. An amount of 10.5 g (59 mmol) of N bromosuccinimide was added and allowed to react for six hours. Then, distilled water was added to stop the reaction and the deposit was filtered. The recovered deposit was purified by column chromatography to obtain 15.97 g (48 mmol) of 9-bromo-10-phenylanthracene. The yield was 89.3%.

후처리

  1. customto react for six hours
  2. distillationThen, distilled water
  3. additionwas added
  4. customthe reaction
  5. filtrationthe deposit was filtered
  6. customThe recovered deposit was purified by column chromatography

출처 및 근거

ORD 기록
ord-56710cff061b48a6b28fa13d1d514b10
출처 데이터셋
uspto-grants-2015_05
특허 번호
US09028976B2

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