Hydrochloric Acid → N1,4,5-Trimethylbenzene-1,2-diamine

HRID 59279노트

반응식

HRID 59279 반응식
[CH3:1][NH:2][C:3]1[CH:8]=[C:7]([CH3:9])[C:6]([CH3:10])=[CH:5][C:4]=1[N+:11]([O-])=O.Cl>[Fe].CO>[CH3:1][NH:2][C:3]1[C:4]([NH2:11])=[CH:5][C:6]([CH3:10])=[C:7]([CH3:9])[CH:8]=1

참가 물질

5

반응물 2

HCID 313Hydrochloric AcidHCID 601943HCID 601943, 화합물

생성물 1

HCID 591611N1,4,5-Trimethylbenzene-1,2-diamine수율 42%

시약·촉매·용매 2

HCID 23925Iron촉매HCID 887Methanol용매

실험 절차

The title compound was prepared according to the procedure described in step-2 of Intermediate-28 by using N1,4,5-trimethyl-2-nitroaniline (0.350 g, 1.9 mmol), methanol (20 mL), Iron powder (1.75 g, 9.75 mmol), conc. HCl (5 mL) to afford 0.120 g of desired product.

후처리

  1. customThe title compound was prepared

출처 및 근거

ORD 기록
ord-b7238f02a1d24982b67171d3245be330
출처 데이터셋
uspto-grants-2016_09
특허 번호
US09439890B2

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