4-Chlorophenyl Isocyanate → methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate

HRID 597620

반응식

HRID 597620 반응식
[NH2:1][C:2](=[N:5][C:6](=[O:9])[O:7][CH3:8])[O:3][CH3:4].NC(=NC(=O)OC)SC.[Cl:19][C:20]1[CH:25]=[CH:24][C:23]([N:26]=[C:27]=[O:28])=[CH:22][CH:21]=1>C(Cl)Cl>[Cl:19][C:20]1[CH:25]=[CH:24][C:23]([NH:26][C:27](=[O:28])[NH:1][C:2](=[N:5][C:6]([O:7][CH3:8])=[O:9])[O:3][CH3:4])=[CH:22][CH:21]=1

참가 물질

5

반응물 3

HCID 76934-Chlorophenyl IsocyanateHCID 2935781-methoxycarbonyl-S-methylisothioureaHCID 53429793N-carbomethoxy-O-methylisourea

생성물 1

HCID 54018948methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate

시약·촉매·용매 1

HCID 6344Dichloromethane용매

실험 절차

To 13 parts of methyl N-(1-amino-1-methoxymethylene)-carbamate, m.p. 36°-39.5°, prepared similar to the procedure in Example 3 for methyl N-(1-amino-1-methylthiomethylene)-carbamate in 140 parts of methylene chloride is added 15 parts of p-chlorophenyl isocyanate. The reaction mixture is stirred overnight and the solution filtered to give 10 parts of methyl 4-(p-chlorophenyl)-N-methoxycarbonylallophanimidate melting at 170° dec.

후처리

  1. filtrationthe solution filtered

출처 및 근거

ORD 기록
ord-70ff63c298bc4898ad7d5f35496eca79
출처 데이터셋
uspto-grants-1977_03
특허 번호
US04014924

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