Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Ethanol → Bis(diisopropylamino)chlorophosphine
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Ethanol | HCID 702 | — |
| 반응물 | Diisopropylamine | HCID 7912 | — |
| 반응물 | Phosphorus trichloride | HCID 24387 | — |
| 반응물 | Bis(diisopropylamino)-phosphine | HCID 498731 | — |
| 용매 | Toluene | HCID 1140 | — |
| 생성물 | Bis(diisopropylamino)chlorophosphine | HCID 2733425 | — |
반응 단계
Bis(diisopropylamino)chlorophosphine was synthesized by reacting phosphorous trichloride and diisopropylamine in toluene. Fifty ml of the resulting bis(diisopropylamino)phosphine was placed in a 250 ml flask and 3.01 ml of ethanol added slowly over a two minute period and the reaction allowed to proceed for several days. After filtering the mixture and removing the solvent, the structure of the bis(diisopropylamino)ethylphosphite ester reagent was analyzed by 31P and 1H NMR (31P NMR in CD3CN 125.9 ppm).
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US07897338B2 |
| 출처 데이터셋 | uspto-grants-2011_03 |
| ORD ID | ord-091c74c35b4a4bfb922d1afbbb81ec01 |
| 출처 메모 | uspto-grants-2011_03 |