Sodium borohydride → HCID 86761287, 화합물

HRID 601096노트

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HRID 601096 반응식
C(C1C=C(C(C)(C)C)C=C(CNC2C(Br)=CC=CC=2Br)C=1O)(C)(C)C.[BH4-].[Na+].[C:28]([C:32]1[CH:37]=[C:36]([C:38]([CH3:41])([CH3:40])[CH3:39])[CH:35]=[C:34]([CH:42]=[N:43][C:44]2[C:49]([F:50])=[C:48]([F:51])[C:47]([F:52])=[C:46]([F:53])[C:45]=2[F:54])[C:33]=1[OH:55])([CH3:31])([CH3:30])[CH3:29]>>[C:28]([C:32]1[CH:37]=[C:36]([C:38]([CH3:41])([CH3:40])[CH3:39])[CH:35]=[C:34]([CH2:42][NH:43][C:44]2[C:49]([F:50])=[C:48]([F:51])[C:47]([F:52])=[C:46]([F:53])[C:45]=2[F:54])[C:33]=1[OH:55])([CH3:29])([CH3:30])[CH3:31]

참가 물질

4

반응물 3

HCID 4311764Sodium borohydrideHCID 866276672,4-Bis(tert-butyl)-6-[[(2,6-dibromophenyl)amino]methyl]phenolHCID 1355098942,4-Di-tert-butyl-6-[(pentafluoroanilino)methylidene]cyclohexa-2,4-dien-1-one

생성물 1

HCID 86761287HCID 86761287, 화합물

실험 절차

Using an analogous procedure to the synthesis of 2,4-bis(tert-butyl)-6-[[(2,6-dibromophenyl)amino]methyl]phenol described above, NaBH4 (1.2 g) was added to a solution of 2,4-bis(tert-butyl)-6-[[(2,3,4,5,6-pentafluorophenyl)imino]methyl]phenol (0.5 g, 1.25 mmol). The product was isolated as an air sensitive white solid, and stored under nitrogen. Yield 0.48 g, 95%.

후처리

  1. customThe product was isolated as an air sensitive white solid

출처 및 근거

ORD 기록
ord-cf383229a0df4fa59e8081ce6158a8fb
출처 데이터셋
uspto-grants-2011_03
특허 번호
US07902308B2

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