반응식
COc1ccc(Cl)cc1.OB(O)c1ccc(C(F)(F)F)cc1>C1=C\CC/C=C\CC/1.C1=C\CC/C=C\CC/1.C1COCCO1.CC(C)(C)P(C1CCCCC1)C1CCCCC1.O.O=P([O-])([O-])[O-].[K+].[K+].[K+].[Ni]>COc1ccc(-c2ccc(C(F)(F)F)cc2)cc1참가 물질
8
반응물 2
생성물 1
시약·촉매·용매 5
반응 조건
- 온도
- 60 °C
실험 절차
pre-ligate Ni(cod)2 and phosphine ligand in dioxane for 15 minutes in a separate plate
후처리
- additionDilute with acetonitrile
- aliquot기록된 절차가 없습니다
- customDiluent solution was made in 1 L batches with 950 mL acetonitrile, 25 mL water, 25 mL glacial acetic acid, and 53 mg 4,4’-di-tert-butylbiphenyl as an external standard (0.2 equiv standard per reaction). Aliquot taken from each well (47 ul) is added into 753 ul of diluent solution
출처 및 근거
- ORD 기록
- ord-cd5fad987da0423e8a602787ffc93d74
- 출처 데이터셋
- Ni-catalyzed Suzuki Miyaura cross-coupling
- 원본 링크
- 출처 보기
연결된 노트
불러오는 중…