Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
1,2-Benzenedicarboxylic acid, 4-nitro-, 1,2-dimethyl ester → Dimethyl 4-(3-pyridyloxy)phthalate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | 1,2-Benzenedicarboxylic acid, 4-nitro-, 1,2-dimethyl ester | HCID 69119 | — |
| 반응물 | 3-Hydroxypyridine sodium salt | HCID 66796471 | — |
| 용매 | Dimethylformamide | HCID 6228 | — |
| 생성물 | Dimethyl 4-(3-pyridyloxy)phthalate | HCID 19595674 | — |
반응 단계
Dimethyl 4-nitrophthalate was reacted in DMF with 3-hydroxypyridine sodium salt in analogy to a process known from the literature (J. Org. Chem. Vol. 42, No. 21, 1977, 3419-3425) to give dimethyl 4-(3-pyridyloxy)phthalate. After standard working up and chromatography using hexane/EA, the diester was isolated as a yellowish oil.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US06005010 |
| 출처 데이터셋 | uspto-grants-1999_12 |
| ORD ID | ord-b39331cc2a22480bb61db833342b2693 |
| 출처 메모 | uspto-grants-1999_12 |