Acrylamide → Prop-2-enamide;styrene

HRID 613193

반응식

HRID 613193 반응식
[Cl-].C[N+](C)(C)CCOC(=O)C=C.[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:21]([NH2:25])(=[O:24])[CH:22]=[CH2:23]>C(O)(C)C>[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1.[C:21]([NH2:25])(=[O:24])[CH:22]=[CH2:23]

참가 물질

5

반응물 3

HCID 6579AcrylamideHCID 7501StyreneHCID 162071Ethanaminium, N,N,N-trimethyl-2-[(1-oxo-2-propen-1-yl)oxy]-, chloride (1:1)

생성물 1

HCID 168235Prop-2-enamide;styrene

시약·촉매·용매 1

HCID 3776Isopropanol용매

반응 조건

온도
75 °C

실험 절차

To a 500 mL round-bottom, three-neck flask fitted with a thermocouple, reflux condenser, and septum was added 150 mL of isopropanol followed by 16.13 g of a 50% aqueous solution of 2-trimethylammonioethylacrylate chloride, 8.06 g of styrene, and 8.06 g of acrylamide. The solution was purged with nitrogen for 1 hour and 0.5 g AIBN was added. The mixture was purged for ~ 15 minutes until all of the AIBN dissolved. The solution was heated to 75° C. under nitrogen for 16 hours.

후처리

  1. customTo a 500 mL round-bottom, three-neck flask fitted with a thermocouple
  2. temperaturereflux condenser
  3. customThe solution was purged with nitrogen for 1 hour
  4. addition0.5 g AIBN was added
  5. customThe mixture was purged for ~ 15 minutes until all of the AIBN
  6. dissolutiondissolved

출처 및 근거

ORD 기록
ord-0c0d54069c9342cabf35f5871433f414
출처 데이터셋
uspto-grants-1999_12
특허 번호
US06007803

연결된 노트

불러오는 중…