m-Chloroperbenzoic acid → HCID 178504633, 화합물
반응식
[NH2:1][C:2]1[NH:3][S:4](=[O:13])(=[O:12])[N:5]=[C:6]([CH2:8][CH2:9][S:10][CH3:11])[N:7]=1.ClC1C=CC=C(C(OO)=[O:22])C=1>CO.C(Cl)(Cl)Cl>[NH2:1][C:2]1[NH:3][S:4](=[O:13])(=[O:12])[N:5]=[C:6]([CH2:8][CH2:9][S:10]([CH3:11])=[O:22])[N:7]=1참가 물질
5
실험 절차
To a solution of 3-amino-5-[2-(methylthio)ethyl]-1,2,4,6-thiatriazine-1,1-dioxide (1.22 gm, 5.5 mmol) in warm methanol (20 ml) there was added dropwise a solution of 80% pure m-chloroperbenzoic acid (1.2 gm, 5.6 mmol) in chloroform (20 ml). The product crystallized from solution during the addition and was collected by filtration and washed with diethyl ether to give 1.27 gm of pure product, m.p. 180°-182° C.
후처리
- customThe product crystallized from solution during the addition
- filtrationwas collected by filtration
- washwashed with diethyl ether
출처 및 근거
- ORD 기록
- ord-bf78132cdaa44872836e427e004f87b4
- 출처 데이터셋
- uspto-grants-1985_02
- 특허 번호
- US04497810
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