Methoxycarbonyl isothiocyanate → 1-(3-Methoxycarbonyl-2-thioureido)-5-methylthio-2-nitrobenzene

HRID 616095

반응식

HRID 616095 반응식
[NH2:1][C:2]1[CH:7]=[C:6]([S:8][CH3:9])[CH:5]=[CH:4][C:3]=1[N+:10]([O-:12])=[O:11].[CH3:13][O:14][C:15]([N:17]=[C:18]=[S:19])=[O:16]>CC(C)=O>[CH3:13][O:14][C:15]([NH:17][C:18](=[S:19])[NH:1][C:2]1[CH:7]=[C:6]([S:8][CH3:9])[CH:5]=[CH:4][C:3]=1[N+:10]([O-:12])=[O:11])=[O:16]

참가 물질

4

반응물 2

HCID 552246Methoxycarbonyl isothiocyanateHCID 105354825-(Methylthio)-2-nitroaniline

생성물 1

HCID 203710131-(3-Methoxycarbonyl-2-thioureido)-5-methylthio-2-nitrobenzene

시약·촉매·용매 1

HCID 180Acetone용매

실험 절차

1.5 G. 2-amino-4-methylthio-1-nitrobenzene in 30 ml. acetone is treated with 2.5 g. methoxy carbonyl isothiocyanate. After five days the mixture is stripped under vacuum and the residue triturated with methanol yielding 1-(3-methoxycarbonyl-2-thioureido)-5-methylthio-2-nitrobenzene.

후처리

  1. customthe residue triturated with methanol

출처 및 근거

ORD 기록
ord-e2419b17992a4f959a0d94d29c9744de
출처 데이터셋
uspto-grants-1978_02
특허 번호
US04072696

연결된 노트

불러오는 중…