Potassium Hydroxide → 2-t-Butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane

HRID 616582

반응식

[C:1]([N:5]=[N:6][C:7](Cl)([CH2:9][C:10]([O:13][CH3:14])([CH3:12])[CH3:11])[CH3:8])([CH3:4])([CH3:3])[CH3:2].[C:16]([O:21][OH:22])([CH2:19][CH3:20])([CH3:18])[CH3:17].[OH-].[K+].C(N=NC(O)(CC(OC)(C)C)C)(C)(C)C>>[C:1]([N:5]=[N:6][C:7]([O:22][O:21][C:16]([CH2:19][CH3:20])([CH3:18])[CH3:17])([CH2:9][C:10]([O:13][CH3:14])([CH3:12])[CH3:11])[CH3:8])([CH3:4])([CH3:3])[CH3:2]

참가 물질

반응물 4

HCID 14797Potassium Hydroxide

HCID 76962tert-Amyl hydroperoxide

HCID 203679222-t-Butylazo-2-hydroxy-4-methoxy-4-methylpentane

HCID 23344765(E)-1-tert-Butyl-2-(2-chloro-4-methoxy-4-methylpentan-2-yl)diazene

생성물 1

HCID 203679062-t-Butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane

실험 절차

The 2-t-butylazo-2-(t-amylperoxy)-4-methoxy-4-methylpentane was prepared in 97% crude yield from 7.78 grams (0.0331 moles) of 2-t-butylazo-2-chloro-4-methoxy-4-methylpentane, 5.35 grams (0.0464 moles) of 90% t-amyl hydroperoxide and 7.92 grams (0.0353 moles) of 25% potassium hydroxide solution. The procedure was the same as that described in Example XX. The infrared spectrum of the product indicated there was a small amount of 2-t-butylazo-2-hydroxy-4-methoxy-4-methylpentane present in the product.

출처 및 근거

ORD 기록: ord-dcfe7a064a2a46a49157193b35d6a997
출처 데이터셋: uspto-grants-1978_02
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04075199

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