Triphenylphosphine → Decyltriphenylphosphonium bromide

HRID 617858노트

반응식

HRID 617858 반응식
[Br-:1].[CH3:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[C:12]1([P:18]([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)[C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1>>[Br-:1].[CH2:2]([P+:18]([C:19]1[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=1)([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[C:12]1[CH:13]=[CH:14][CH:15]=[CH:16][CH:17]=1)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11]

참가 물질

3

반응물 2

HCID 11776TriphenylphosphineHCID 18759729Decane bromide

생성물 1

HCID 3084561Decyltriphenylphosphonium bromide

실험 절차

Decane bromide (7.0 g) and 10 g of triphenylphosphine were stirred at 120° C. under a nitrogen atmosphere for 8 hours. The mixture was recrystallized from acetone-ether to give 14.4 g of colorless, crystalline decyltriphenylphosphonium bromide. IRνmax (CHCl3): 2920, 2850, 1440, 1120, 1000, 680 cm-1

후처리

  1. customThe mixture was recrystallized from acetone-ether

출처 및 근거

ORD 기록
ord-3075facca349438ba2ee1659417732c0
출처 데이터셋
uspto-grants-1999_09
특허 번호
US05952316

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