Toluene → 1-tert-Butyl-2,5-dichloro-4-methylbenzene

HRID 620958노트

반응식

HRID 620958 반응식
[Cl-:1].[Al+3].[Cl-:3].[Cl-].[C:5]1([CH3:11])[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1>>[Cl:1][C:6]1[CH:7]=[C:8]([C:5]([CH3:11])([CH3:10])[CH3:6])[C:9]([Cl:3])=[CH:10][C:5]=1[CH3:11]

참가 물질

3

반응물 2

HCID 1140TolueneHCID 6451240Aluminum(III) Chloride

생성물 1

HCID 144188301-tert-Butyl-2,5-dichloro-4-methylbenzene수율 270.8%

실험 절차

After adding a large excess of 2000 g of toluene and 64 g (0.48 mol) of anhydrous aluminum chloride, as a catalyst, to 284 g (1.3 mol) of 2,5-dichloro-4-t-butyltoluene obtained as stated above, the mixture was brought into reaction for 5 hours at room temperature under a vigorous agitation thereof.

출처 및 근거

ORD 기록
ord-7d240177babf4591935d6a2ff34f315a
출처 데이터셋
uspto-grants-1989_04
특허 번호
US04822928

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