Hydrazine hydrate (1:1) → HCID 68750341, 화합물

HRID 624157노트

반응식

HRID 624157 반응식
[NH2:1][C:2]1[CH:18]=[CH:17][C:5]([C:6]([C:8]2[CH2:13][CH2:12][CH2:11][CH2:10][C:9]=2[C:14](O)=[O:15])=O)=[CH:4][CH:3]=1.O.[NH2:20][NH2:21]>C(O)C>[NH2:1][C:2]1[CH:18]=[CH:17][C:5]([C:6]2[C:8]3[CH2:13][CH2:12][CH2:11][CH2:10][C:9]=3[C:14](=[O:15])[NH:21][N:20]=2)=[CH:4][CH:3]=1

참가 물질

4

반응물 2

HCID 24654Hydrazine hydrate (1:1)HCID 68750696HCID 68750696, 화합물

생성물 1

HCID 68750341HCID 68750341, 화합물

시약·촉매·용매 1

HCID 702Ethanol용매

실험 절차

10.3 g of 2-(4-amino-benzoyl)-cyclohex-1-enecarboxylic acid (42 mmol) were dissolved in 45 mL ethanol, 2.7 g (54 mmol) hydrazine hydrate was added and the mixture was heated under reflux for 30 hours. Precipitation of the product already started several hours after heating. After cooling in the refrigerator overnight the precipitated product was filtered and washed with cold ethanol.

후처리

  1. temperaturethe mixture was heated
  2. temperatureunder reflux for 30 hours
  3. customPrecipitation of the product already started several hours
  4. temperatureafter heating
  5. temperatureAfter cooling in the refrigerator overnight the precipitated product
  6. filtrationwas filtered
  7. washwashed with cold ethanol

출처 및 근거

ORD 기록
ord-966dbe9931bb46c0835769b3c753dac0
출처 데이터셋
uspto-grants-2016_04
특허 번호
US09302989B2

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