참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | 1-Chloro-4-nitrobenzene | HCID 7474 | — |
| 반응물 | Sodium Carbonate | HCID 10340 | — |
| 반응물 | Potassium Acetate | HCID 517044 | — |
| 용매 | 1-Butanol | HCID 263 | — |
| 생성물 | 1,1'-Oxybis(4-nitrobenzene) | HCID 7568 | — |
반응 단계
A 250 ml shaker bomb is charged with 79 g (0.50 mole) p-nitrochlorobenzene, 43 g n-butanol, 3 g (0.03 mole) potassium acetate, and 30 g (0.28 mole) sodium carbonate. The reactor is purged with nitrogen and heated to and maintained at 200° C. under autogenous pressure for 9 hours. No increase in pressure is observed and no 4,4'-dinitrodiphenyl ether is formed. This example illustrates that the reaction will not proceed using a protic solvent.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04558164 |
|---|
| 출처 데이터셋 | uspto-grants-1985_12 |
|---|
| ORD ID | ord-75fdddeaadc445858041a462c4163a6b |
|---|
| 출처 메모 | uspto-grants-1985_12 |
|---|
