Hydrochloric Acid → Methyl 6-oxohexanoate

HRID 64589

반응식

HRID 64589 반응식
[CH3:1][O:2][C:3](=[O:13])[CH2:4][CH2:5][CH2:6][CH2:7][CH:8](OC)[O:9]C.Cl>CO>[C:3]([CH2:4][CH2:5][CH2:6][CH2:7][CH:8]=[O:9])([O:2][CH3:1])=[O:13]

참가 물질

4

반응물 2

HCID 313Hydrochloric AcidHCID 11041551Methyl 6,6-dimethoxyhexanoate

생성물 1

HCID 81164Methyl 6-oxohexanoate

시약·촉매·용매 1

HCID 887Methanol용매

실험 절차

After the reaction, MeOH was recovered, following by the same treatment as above to give 9.47 g. of crude 6,6-dimethoxycaproic acid methyl ester. Then, a 10 wt.% aqueous hydrochloric acid solution was added to this crude product, followed by stirring for 6 hours at room temperature. The reaction mixture was treated by usual method to give crude products. Pure 3.20 g. of 5-carbomethoxy-1-pentanal was obtained by column chromatography.

후처리

  1. customwas recovered
  2. customto give 9.47 g
  3. additionThe reaction mixture was treated by usual method
  4. customto give crude products

출처 및 근거

ORD 기록
ord-18e99ebb93034446a33f27fb49e9b384
출처 데이터셋
uspto-grants-1986_09
특허 번호
US04609492

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