Methyldichlorosilane → Silane, dichloro-5-hexen-1-ylmethyl-

반응식

[CH2:1]=[CH:2][CH2:3][CH2:4][CH:5]=[CH2:6].[CH3:7][SiH:8]([Cl:10])[Cl:9]>>[CH2:1]([Si:8]([CH3:7])([Cl:10])[Cl:9])[CH2:2][CH2:3][CH2:4][CH:5]=[CH2:6]

참가 물질

반응물 2

HCID 6376Methyldichlorosilane2회

HCID 115981,5-Hexadiene

생성물 1

HCID 11063373Silane, dichloro-5-hexen-1-ylmethyl-수율 87.6%

반응 조건

온도: 40 °C

실험 절차

5-Hexenylmethyldichlorosilane was prepared by combining 1,5-hexadiene (160 g, 1.95 m), 0.1 g of a platinum complex ##STR1## and methyldichlorosilane (5 g) in a flask equipped with a condenser and a thermometer. The mixture was heated to 40° C. to initiate the reaction. Additional methyldichlorosilane (120 g) was added dropwise to the mixture so that the temperature was kept below 55° C. The product was isolated in 87.6% yield by distillation under reduced pressure (bp 67°-9° C./2 mm Hg).

후처리

customequipped with a condenser
customthe reaction
customwas kept below 55° C
customThe product was isolated in 87.6% yield by distillation under reduced pressure (bp 67°-9° C./2 mm Hg)

출처 및 근거

ORD 기록: ord-3130f4ffee2a4a87bfd4963f21ea6fd7
출처 데이터셋: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04609574

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