1,5-Hexadiene → 5-Hexenyldimethylchlorosilane

반응식

[CH2:1]=[CH:2][CH2:3][CH2:4][CH:5]=[CH2:6].[CH3:7][SiH:8]([CH3:10])[Cl:9]>>[CH2:1]([Si:8]([CH3:10])([CH3:7])[Cl:9])[CH2:2][CH2:3][CH2:4][CH:5]=[CH2:6]

참가 물질

반응물 2

HCID 115981,5-Hexadiene

HCID 66108Chlorodimethylsilane

생성물 1

HCID 118299765-Hexenyldimethylchlorosilane수율 68%

실험 절차

5-Hexenyldimethylchlorosilane was prepared by combining 1,5-hexadiene (164 g) and 0.05 g of platinum complex ##STR3## in a flask equipped with a condenser, addition-funnel and a thermometer. Dimethylchlorosilane (92 g) was added at such a rate that the pot temperature did not rise above 40° C. The mixture was allowed to stand at room temperature for 48 hours. The product was isolated in 68% yield by distillation under reduced pressure (bp 39°-40° C./2.2 mm Hg).

후처리

customequipped with a condenser, addition-funnel
customdid not rise above 40° C
customThe product was isolated in 68% yield by distillation under reduced pressure (bp 39°-40° C./2.2 mm Hg)

출처 및 근거

ORD 기록: ord-bf32446cab8e43dd9749a48c248b3765
출처 데이터셋: uspto-grants-1986_09
DOI: 10.6084/m9.figshare.5104873.v1
특허 번호: US04609574

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