Oleic Acid → Oleyl Alcohol

HRID 647756

반응식

HRID 647756 반응식
[C:1]([OH:20])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[H][H]>>[C:1]([O:20][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[CH2:1]([OH:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8]/[CH:9]=[CH:10]\[CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]

참가 물질

4

반응물 2

HCID 445639Oleic AcidHCID 178418361HCID 178418361, 화합물

생성물 2

HCID 5284499Oleyl AlcoholHCID 5364672Oleyl Oleate

실험 절차

As in the preceeding examples, 200 grams of oleic acid and 10 grams of the catalyst system prepared according to the above paragraph were treated in a manner similar to that set forth in Example I above, that is, by reaction at a temperature of 300° C. and a pressure of 1000 psi of hydrogen for a period of 4 hours. After the 4 hour reaction period had elapsed, heating was discontinued, the autoclave was allowed to return to room temperature, and the excess pressure was vented. Analysis of the reaction product after separation from the catalyst disclosed that there had been a 94% reduction of the carboxyl moieties to form oleyl oleate, oleyl alcohol as well as geometric and positional isomers thereof with an 83% reduction of the double bond.

후처리

  1. additionwere treated in a manner similar to that set forth in Example I above
  2. customthat is, by reaction at a temperature of 300° C.
  3. customAfter the 4 hour reaction period
  4. temperatureheating
  5. customto return to room temperature
  6. customAnalysis of the reaction product after separation from the catalyst

출처 및 근거

ORD 기록
ord-4ebdeb303e43432b8d95421ed166a0f6
출처 데이터셋
uspto-grants-1983_10
특허 번호
US04410460

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