Methyl Methacrylate → 2-Morpholinoethyl methacrylate

HRID 648438

반응식

HRID 648438 반응식
[O:1]1[CH2:6][CH2:5][N:4]([CH:7](O)[CH3:8])[CH2:3][CH2:2]1.C[O-].[Na+].COC1C=CC(O)=CC=1.[C:22]([O:27]C)(=[O:26])[C:23]([CH3:25])=[CH2:24]>>[C:22]([O:27][CH2:8][CH2:7][N:4]1[CH2:5][CH2:6][O:1][CH2:2][CH2:3]1)(=[O:26])[C:23]([CH3:25])=[CH2:24]

참가 물질

5

반응물 4

HCID 6658Methyl MethacrylateHCID 90154-MethoxyphenolHCID 30293761-MorpholinoethanolHCID 10942334Sodium Methoxide

생성물 1

HCID 763432-Morpholinoethyl methacrylate

실험 절차

A 1000 ml resin kettle was equipped with a still head, air bubbler, and thermometer. The kettle was placed in a regulated water bath, set at 80°. 750 ml methyl methacrylate was added to the kettle followed by a solution containing 250 g morpholinoethanol, 5.0 g sodium methoxide and 0.5 g p-methoxyphenol. During the 120 minute reaction time, air was bubbled slowly through the vigorously stirred solution. After 30 and 60 minutes, 5.0 g sodium methoxide was added. At the end of the reaction time, the mixture was cooled and neutralized with 17.0 g glacial acetic acid.

후처리

  1. customThe kettle was placed in a regulated water bath
  2. customset at 80°
  3. customDuring the 120 minute reaction time, air
  4. customwas bubbled slowly through the vigorously stirred solution
  5. additionAfter 30 and 60 minutes, 5.0 g sodium methoxide was added
  6. temperatureAt the end of the reaction time, the mixture was cooled

출처 및 근거

ORD 기록
ord-d6eca69985684e6b93071ee8a3460f9f
출처 데이터셋
uspto-grants-1988_04
특허 번호
US04735887

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