Triethylamine → 3-Vinyldimethylsilyl-2-oxazolidinone

HRID 648762노트

반응식

HRID 648762 반응식
[O:1]1[CH2:5][CH2:4][NH:3][C:2]1=[O:6].[CH:7]([Si:9]([CH3:12])([CH3:11])Cl)=[CH2:8].C(N(CC)CC)C>O1CCCC1>[CH:4]([N:3]1[CH:7]([SiH:9]([CH3:12])[CH3:11])[CH2:8][O:6][C:2]1=[O:1])=[CH2:5]

참가 물질

5

반응물 3

HCID 8471TriethylamineHCID 739492-OxazolidinoneHCID 519368Chloro(dimethyl)vinylsilane

생성물 1

HCID 1317154863-Vinyldimethylsilyl-2-oxazolidinone

시약·촉매·용매 1

HCID 8028Tetrahydrofuran용매

실험 절차

A 3-vinyldimethylsilyl-2-oxazolidinone was prepared in accordance with the following procedure. A mixture of 34.8 grams of 2-oxazolidinone and 48.17 grams of vinyldimethylchlorosilane was prepared in 750 ml of tetrahydrofuran solvent. 40.26 grams of triethylamine was added dropwise. The mixture was then heated in a distillation apparatus with continuous reflux for a period of 30 minutes.

후처리

  1. temperatureThe mixture was then heated in a distillation apparatus
  2. temperaturewith continuous reflux for a period of 30 minutes

출처 및 근거

ORD 기록
ord-b469417e4ceb4c9baeefa2b560fdf6e7
출처 데이터셋
uspto-grants-1988_04
특허 번호
US04736046

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