CAS 1719-58-0 Chloro(dimethyl)vinylsilane (HCID 519368)

이름 및 식별자

우선 이름: Chloro(dimethyl)vinylsilane
IUPAC: chloro-ethenyl-dimethylsilane
현지명: 클로로디메틸비닐실란
영어명: Chlorodimethylvinylsilane
분자식: C4H9ClSi
분자량: 120.65

이름 및 동의어

Chlorodimethylvinylsilane1719-58-0DimethylvinylchlorosilaneVinyldimethylchlorosilaneChloro(dimethyl)vinylsilaneSilane, chloroethenyldimethyl-Vinylchlorodimethylsilanevinyldimethylsilyl chloridedimethylchlorovinylsilaneDTXSID5042378XJA6N5221Tdimethylvinylsilyl chloride

이름 더 보기

클로로다이메틸비닐실레인클로로디메틸비닐실란클로로에테닐디메틸실란DK581DK109CV-4720DMVS-ClDIMETHYLVINYLSILYLCHLORID

EINECS 217-007-1AI3-25204Stannane, chloroethenyldimethyl-DTXCID3022378EC 217-007-1RefChem:575717Silane, chloroethenyldimethyl217-007-1

데이터베이스 식별자

CAS: 1719-58-0
PubChem CID: 519368
DTXSID: DTXSID5042378
ChEMBL: CHEMBL3561435
UNII: XJA6N5221T
EC Number: 217-007-1
Nikkaji: J203.112D

물성

구조 계산 물성

극성 표면적: 0 Å²
수소 결합 공여자 수: 0
수소 결합 수용자 수: 0
회전 가능 결합 수: 1
무거운 원자 수: 6
형식 전하: 0
복잡도: 58.6

실험 및 물리화학적 성질

Chemical ClassesToxic Gases & Vapors -> Chlorosilanes

SpringerMaterials Properties29Si nuclear magnetic resonance spectrum

Physical Description · 2건

Liquid

Colorless or brown liquid; [Alfa Aesar MSDS]

물리화학적 성질

끓는 점: 82 · 82-83 °C(lit.)
밀도: 0.874 g/mL · 0.874 g/mL at 25 °C(lit.)
증기압: 95 hPa · 95hPa at 20℃
굴절률: 20 · n20/D 1.414(lit.)
인화점: 23 °F · 23 °F
저장 조건: 2 · Inert atmosphere,2-8°C
용해도: 2 Cl2 · most aprotic organic solvents, but CH2Cl2 is most commonly used; reacts with H2O and other protic solvents.
물리적 상태: 투명한 액체
색상: Colorless to Light yellow to Light orange
Specific Gravity: 0.884 · 0.884
수용성: 물과 반응합니다.
BRN: 1737688 · 1737688
InChI: 1S/C4H9ClSi/c1-4-6(2,3)5/h4H,1H2,2-3H3
InChIKey: XSDCTSITJJJDPY-UHFFFAOYSA-N
SMILES: C[Si](C)(Cl)C=C
NIST: Vinyldimethylchlorosilane(1719-58-0)
EPA: Silane, chloroethenyldimethyl- (1719-58-0)

화학적 성질

clear light beige to amber liquid

안전 및 규제

GHS 분류

GHS Classification · 4건

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 132 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

유해성 정보

Regulatory Information · 4건

Chemical: Silane, chloroethenyldimethyl-

Silane, chloroethenyldimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, chloroethenyldimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 16-05-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/16026

Silane, chloroethenyldimethyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards SummaryReacts with water; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Trichlorovinylsilane. See Vinyltrimethylsilane.

Hazard Classes and CategoriesFlam. Liq. 2 (100%)

안전 및 보호

Exposure Control and Personal Protection · 1건

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

독성 정보

Adverse EffectsDermatotoxin - Skin burns.

안전 데이터

wgk: 1
tsca: TSCA listed
ridadr: UN 2985 3/PG 2
HS 번호: 29319090
risk_code: 11-14-34
hazard_code: F,C
safety_code: 16-26-33-36/37/39-45-25
포장분류: II
위험 등급: 3
F 고인화성물질: 1-10
Hazard Classifications: Flam. Liq. 2Skin Corr. 1B
스토리지 클래스: 3 - Flammable liquids
함량 및 규제정보: 물질구분: 유독물질; 혼합물(제품)함량정보: 클로로에테닐디메틸실란 및 이를 25% 이상 함유한 혼합물
유해화학물질 필터링: 2017-1-782(신규화학물질)

화학 및 산업

용도 및 제조

U.S. Production2023: 1,000,000 - <8,500,000 lb

Industry UsesIntermediate

General Manufacturing Information · 2건

All Other Basic Inorganic Chemical Manufacturing

Silane, chloroethenyldimethyl-: ACTIVE

응용 분야 · 2건

용도Metallacycloalkanones have been prepared by the cyclic hydroboration of dialkenyl silanes. In order to obtain one such dialkenyl silane, chlorodimethylvinylsilane was allylated with allyl magnesium bromide (eq 4).The dialkenyl silane was then hydroborated sequentially with thexylborane, followed by treatment with potassium cyanide, trifluoroacetic anhydride, and finally hydrogen peroxide in sodium hydroxide to produce the silacycloheptanone (eq 4).Cyclic silylketones were then further reacted to form acyclic compounds with chiral centers that are difficult to introduce without the use of the silicon tether.

일반 설명Chloro(dimethyl)vinylsilane (Dimethylvinylchlorosilane, Vinyldimethylchlorosilane, C4H9ClSi) is an organosilicon compound. It participates in the preparation of 1,1,2,2-tetramethyl-1,2-divinyldisilane. It undergoes [2+4] cycloaddition reaction with t-butyllithium in the presence of 2,3-dimethyl-1,3-butadiene to afford cycloadducts.