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Bromine → (R)-(-)-5-Bromo-2-(1-methylheptyloxy)benzonitrile

HRID 651306
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반응식

HRID 651306 반응식
[CH3:1][C@@H:2]([O:9][C:10]1[CH:17]=[CH:16][CH:15]=[CH:14][C:11]=1[C:12]#[N:13])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].BrBr.[Br:20]C1C=CC(OC[C@@H](C)CC)=C(C=1)C#N>C(Cl)(Cl)Cl>[Br:20][C:15]1[CH:16]=[CH:17][C:10]([O:9][C@H:2]([CH3:1])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8])=[C:11]([CH:14]=1)[C:12]#[N:13]
참가 물질실험 절차후처리출처 및 근거반응 노트

참가 물질

5

반응물 3

HCID 24408BromineHCID 21308782(R)-(-)-2-(1Methylheptyloxy)benzonitrileHCID 53787839(S)-(+)-5-Bromo-2-(2-methylbutyloxy)benzonitrile

생성물 1

HCID 53905579(R)-(-)-5-Bromo-2-(1-methylheptyloxy)benzonitrile

시약·촉매·용매 1

HCID 6212Chloroform용매

실험 절차

Quantities: compound 40 (12.34 g, 0.054 mol), bromine (17.15 g, 0.0107 mol), chloroform (100 ml). The experimental procedure was as described for the preparation of compound 41. The crude product was purified by column chromatography (20% petrol/dichloromethane) to give a fawn oil.

후처리

  1. customThe crude product was purified by column chromatography (20% petrol/dichloromethane)
  2. customto give a fawn oil

출처 및 근거

ORD 기록
ord-2852928170f24de9af50cd9536d74e04
출처 데이터셋
uspto-grants-2001_08
DOI
10.6084/m9.figshare.5104873.v1
특허 번호
US06278028B1

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